The short answer to this is no. All inventory is synced to Shopify as soon as there is an update in Pio. This way, you should always see the same stock in both Shopify and Pio.
If you need to export inventory stocks to Excel, you can login to your Shopify admin and go to Inventory. Here you can search and filter the list before exporting it.
Read this article to learn more details of inventory in Pio.